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CALORISED PIPES
In this both
inner and outer surfaces of MS welded pipes are given a
calorising treatment, under high temperature in which
diffusion of aluminium takes place into the surface of the
steel. Subsequently, the calorised pipes are given ceramic
coating on both inner and outer surface. The calorising
treatment and the ceramic coating give these pipes an extra
ordinary higher life and resistance to corrosion at high
temperature than ordinary MS pipes and expensive stainless and
alloy steel pipes normally used in oxygen lancing in electric
arc furnaces and chemical factories and refineries. The
average life of calorised and ceramic coated pipes is 7 - 9
times more than that of ordinary MS pipes and stainless steel
pipes. Calorised and ceramic coated pipes are used in areas
requiring high temperature and corrosive applications as
follows:
They are used
as better and cheaper material of construction in the
following equipments:
- Boilers
- Burners
- Recuperator
- Thermowell
- Soot blower
- Air pre-heater
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- Transfer lines
- Heat Exchangers
- Refinery heater
- Chemical reactors
- Sulphur condensers
- Fluidised bed
exchanger
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SPECIFICATIONS:
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Type I Both
ends threaded with one coupling and one plastic cap. |

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| Type
II Plain ends. |

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| Type
III Plain ends with one pressed coupling. |

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The pipe is a low
carbon special thin walled pipe, with high strength to weight
ratio. The normal bore size and Wall thickness are as per
standards.
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The calorising is
upto a depth of 100 to 150 microns.
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The Refractory
Ceramic coating is of special high Alumina materials to give
higher resistance against spalling at high temperatures.
A comparison between ordinary steel pipes, expensive Alloy Steel Pipes and Stainless Steel pipes under different corrosive conditions is as follows:
It can be seen that calorised pipes are better and economical in comparison with ordinary or alloy steel pipes under various conditions of corrosion and use, which are encountered in different industries.
Why are Calorised Lance Pipes needed in oxygen steel making? In the process of steel manufacturing by open hearth or electric furnace, the consumption rate of lance pipes for oxygen injection sows rather high ratio owing to high temperature and severe oxidation. In general, steel pipes are used as lance pipes for oxygen injection. If MS pipes are treated by this process consumption rate of lance pipes will increase 6 - 7 times. It is necessary to make the pipe fireproof as a first step. Special treatment is then
needed to protect the pipe from any falling-off or scaling-off by
shock or by bending stress. As a result of research conducted over
many years, it was discovered that the most effectual method is to
diffuse aluminium into the pipe's surface, so as to promote wear
proof properties on steel pipe. That is to say, calorising is to be
carried at, in and outside of the steel pipe to promote wear and
fire proof properties of the pipe. To enumerate, the advantages of
oxygen steel making process:
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The exothermic
reaction and agitation promote decarbonisation and heat rise in
the furnace, while foaming slag can be eliminated.
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Fusion of sub
material can be accelerated.
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Quality of steel
will be improved.
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As the process
raises the temperature.
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Selection of raw
materials to be charged becomes easy.
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The process raises
the production capacity of an electric furnace.
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Hydrogen, Nitrogen
and non-metallic inclusions can be eliminated through oxidation.
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It makes it possible
to recover chrome with the use of high chrome steel scrap.
Calorised lance
pipes are prepared by rendering calorising finish to carbon steel in
a thickness of 100-150 microns on both inner and outer surfaces and
further coating with refractory materials in 200-300 microns
thickness on both inner and outer surfaces. This metal diffusion
treatment promotes the fireproof properties of steel pipes. The
diffusion is an inter-metallic bond, which doesn't get damaged
either by mechanical working like bending or straightening or by
high temperatures. In the case of general fireproof pipes, oxidation
takes place at that part of the surface in contact with the flame.
In the case of these metal diffused pipes, the metal existing at the
surface of the diffused zone is oxidised to its respective oxide,
which prevents the further progress of oxidation and also melting.
For instance, in calorising, aluminium is oxidised to alumina, which
has a very high melting point 20500C compared to the
melting point of aluminium, which is mere 6580C.
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As shown in the
image the splashing action of high-pressure oxygen on molten
steel is most severe at the upper inside part of the pipe ('A'
point in the image). At this point the following
reaction takes place.
4 Al + 3 O2 = 2 AL2O3 + 7.608
Calories
This is the
essential difference between general fireproof pipes and metal
diffused pipes. A more effective result is obtained by ceramic
coating on the metal diffused zone. Ceramic means metallic
oxides, carbides, nitrides and also fireproof clay. Alkaline
silicates are added to improve the durability and tenacity. In
the process of ceramic coating it is necessary that he surface
of the metal is diffused zone is rough so that the ceramic
coating has a good bonding and does not get peeled off. |
Ceramic coating is
carried out usually on the inside and outside of the pipe. The
composition of the ceramic coating is as per the kind of furnace
structure and the steel / metal produced. After cleaning the
impurities on the surface of the pipe, aluminium powder or a mixture
of aluminium and iron powder (to which halides are added as flux) is
filled up inside and outside of the pipe and packed in a case. This
then heated from outside. The illustration shows that the mettalic
powder zone (2) adheres to the surface of metal alloy zone (1) on
one side and to ceramic coating zone (3) on the other. Therefore the
Ceramic coating never falls off or scales off from the pipe during
the oxygen injection operation.

Comparison chart
between MS pipe & Calorised pipe.
Oxygen
Charge
Press. Kg/cm2 |
Oxygen
flow
rate m3/min |
Charge
Time
(min.) |
Length
of consumption
mm |
Consumption
rate mm/min. |
Type
of Pipe |
Rate
of MS Pipe to Calo. Lance |
| 6.5-7 |
6.5-5 |
3 |
1950 |
650 |
MS |
1 |
| 6.5-7 |
6.5-5 |
15 |
1290 |
86 |
CL |
7.56 |
| 6.5-7 |
6.5-5 |
15 |
1420 |
94 |
CL |
6.91 |
| 6 |
6 |
3 |
2430 |
809 |
MS |
1 |
| 6 |
6 |
10 |
1150 |
115 |
CL |
7.03 |
| 6 |
6 |
10 |
890 |
89 |
CL |
9.03 |
| 5.5-6 |
5.5 |
3 |
1860 |
620 |
MS |
1 |
| 5.5-6 |
5.5 |
10 |
840 |
84 |
CL |
7.38 |
| 5.5-6 |
5.5 |
10 |
1070 |
107 |
CL |
5.79 |
| 6.6 |
6.3 |
3 |
1830 |
610 |
MS |
1 |
| 6.6 |
6.3 |
10 |
610 |
61 |
CL |
10 |
| 6.6 |
6.3 |
10 |
1070 |
107 |
CL |
5.70 |
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